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Energy Materials

16: Electrical energy from animal dung

Problem:

As all transport transitions to electric propulsion, the increase in the demand for electrical energy will call on a diversity of sources.

Solution:

Anaerobic digesters that convert the dung of horses, cattle, pigs and other livestock to electricity.

Anaerobic digestion is a sequence of processes by which microorganisms break down biodegradable material in the absence of oxygen and create and capture biogas – a flammable fuel with high methane content which  can be used to run turbines and create electricity.

In the Fall of 1998 two ex-Aachen University students from farming families, Hendrik Becker and Jörg Meyer zu Strohe, built an anaerobic digester at a prototype biogas plant feed facility in Münsterland, north-west Westfalen.

Unlike other biogas technology, their innovative solids injection process can operate using  100 percent manure or manure mixed with difficult to process substrates such as straw and grass.

They started a company, PlanET, to manufacture their green dome-shape digesters for use in rural areas.

During the past two decades, PlanET has sold and implemented nearly 480 biogas plants of between 40 kW and several MW to France, the UK, the USA and Canada.

The total electric power of PlanET installations currently in operation is 142,000 kWel. The plant also processes other waste such as that of cereal farmers (the unusable part of the harvest).

Finland

In 2015, Finland’s state energy company, Fortum, led by Anssi Paalanen, also looked at anaerobic digesters as a fuel source and began trials at Lake Järvenpää, gathering raw materials from four stables from Espoo and Kirkkonummi for their units.

They found that the manure and bedding of three horses could provide heat and light for a single-family Finnish home in a colder climate.

Finland has 70,000 horses, enough to provide heat and electricity for up to 23,000 homes. Fortum began with a small plant, with the manure forming just 10% of the wood-shaving mix used for burning.

By autumn, with more stables taking part, the manure proportion was raised to 20%. The number of horses in society is increasing.

According to Statistics Sweden, there are more than 360,000 horses in Sweden, of which three-quarters are situated in urban or near-urban environments. With a dry matter manure content of 40%, this equates to a quantity of 1,500 tons (1,360 tonnes) of horse manure per annum and corresponds to an annual biogas production of 641 GWh.

In 2016, Finland banned the disposal of manure in landfill sites, along with many other organic, biodegradable materials. This meant that stables risked being stuck with a pile of ordure they could not shift.

The manure can be given to farmers for use as fertilizer, but in the EU this is now permitted only on flat fields because of the risk that exists on sloping fields that the manure will leach into water courses. Flat fields are still fair game for muck-spreaders, but the E.U. bans the strewing of horse manure on any sloping site, as a sensible precaution against equine faeces leaching into the water system.

This means that Finland’s manure does not have many places to go, making the manure biomass plan a double win. The Fortum solution, which they called quite simply “HorsePower”, seemed the most logical.

From August 2017, Fortum set up a pilot project in Bergslagen, southern Sweden, requesting manure from the 400-500 horses in the region, the electricity produced going to households in the town of Hällefors.

Fortum was looking for local suppliers and asked that there are at least 10-20 horses in the stable in order to cover transport costs. By the end of the year 3,000 horses were producing energy.

If Fortum could process the manure mix from 280,000 of Sweden’s horses it would be enough to heat all of the houses in Östergötland and Gotland.

Following the 2017 FEI European Equestrian Championships held in the city of Gothenburg in August, Renova, the municipal waste management, created around 360 000 kWh of district heating and 60 000 kWh of electricity, from the estimated 330 tons (300 tonnes) of horse manure and straw left by the 600 horses participating in the competition.

Two months later, Finland’s Horse Show in Helsinki Ice Hall followed suit. During the event, HorsePower delivered wood-based bedding for the 250 or so horses that stayed in temporary stalls, their dung at Fortum’s Järvenpää power plant anaerobically generating 140 kW to meet all of the electricity needs of the event from lighting to scoreboards to support infrastructure. (fortum.com)

According to a report compiled in 2006 by the Food and Agriculture Organization of the United Nations (FAOSTAT), there are an estimated 58 million horses in the world.

In terms of HorsePower potential, one is therefore talking about gigawatts of electricity. If the manure of the world’s horse population were put to work, this would provide electricity for 19.5 million homes or two New York cities, not to mention electric vehicles.

At the beginning of 2016, the global number of four-wheeled electric vehicles in use came to around 13 million units: 6.18 million electrified power trains will be produced by 2020. This does not take in the hundreds of millions of two- and three-wheeled vehicles, particularly in China.

With such a demand for electrical energy, it is inevitable that horse manure – not to mention manure from cattle, pigs and other livestock – will play its part alongside other sustainable energy sources.

Discover solution 17: the new antibiotics.

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Categories
Energy

14: A solar cell that works at night

Problem:

Solar cells cannot function at night.

Solution:

Jeremy Munday and Tristan Deppe at the Department of Electrical and Computer Engineering at the University of California Davis have developed a thermoradiative cell which generates electrical current as it radiates infrared light (heat) toward the night sky and extreme cold of deep space.

ACS Photonics, a publication of the American Chemical Society, says of the illustration at the top of this solution “The Perspective featured depicts a nighttime photovoltaic device that generates power by looking up at the night sky, behaving like a solar cell in reverse.”

The abstract of the research paper on the cell says:

In order to produce electrical power after the sun has set, we consider an alternative photovoltaic concept that uses the earth as a heat source and the night sky as a heat sink, resulting in a “nighttime photovoltaic cell” that employs thermoradiative photovoltaics and concepts from the advancing field of radiative cooling.

Such a cell could generate up to 50 watts of power per square meter under ideal conditions at night, about a quarter of what a conventional solar panel can generate in daytime.

Jeremy Munday and Tristan Deppe, “Nighttime Photovoltaic Cells: Electrical Power Generation by Optically Coupling with Deep Space,” ACS Photonics January 7, 2020.

Discover solution 15: water bomber super scoopers

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Categories
Energy Materials

12: Carbon-free aluminium smelting

Problem:

Nearly all aluminium smelting has for many years been done with hydroelectric power from generators dedicated to the purpose, with the smelters built next to the dams that store the water.

However, smelting is the largest single producer of toxic fluorides worldwide. ‘Scrubbers’ are usually used to remove the majority of fluorides from factory smoke today, but when those scrubbers are spent they are also dumped in landfills where the soluble fluorides absorbed into them can leak out into the soil.

Solution:

In May 2018, Alcoa and Rio Tinto unveiled what they describe as the world’s first carbon-free aluminum smelting process, through a partnership called Elysis, which refers to the electrolysis of alumina, a process at the centre of aluminum smelting.

Apple, which is planning to use the metal in its iPhone and laptop computers, as part of its own efforts to decarbonize its operations and supply chain, is also investing in Elysis.

On August 16, 2019, construction began on the Elysis R&D centre in Quebec’s Saguenay-Lac-Saint Jean region, located within Rio Tinto’s Complexe Jonquière, the site of the Arvida smelter, Vaudreuil refinery and Arvida research and development center.

The project is expected to be fully operational by the second half of 2020, employing 25 technical experts.

By 2024, commercialisation on a world scale could eliminate the equivalent of 7 million tons (6.5 million tonnes) of GHG emissions if fully implemented at existing aluminum smelters in Canada – roughly equal to taking nearly 1.8 million light-duty vehicles off the road. (alcoa.com)

Meanwhile, Russian aluminum giant Rusal En+, which uses hydropower from rivers in Siberia to power most of its smelters, is targeting 2021 to roll out its own line of carbon-free aluminum, based on an inert anode system.

Rusal has teamed up with US manufacturer Braidy Industries to build a mill in Kentucky, which will be the world’s largest low-carbon rolled aluminum producer, as well as the first new greenfield aluminum mill in 37 years to be constructed in the United States.

En+ Group, the holding company for Rusal reckons the trend for lighter and more efficient electric car bodies will boost demand for “green” aluminum. (enplusgroup.com/en)

Discover solution 13: floating neighbourhoods that can adapt to changes in water level

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Categories
Energy

8: AWES aircraft that generate electricity

Problem:

Land-based generation of electricity is limited.

Solution:

Alongside aircraft using electricity, there are also aircraft which will be used to regularly generate electricity.  The technology is known as AWES: Airborne Wind Energy Systems.

It was in 1978 that Mi. L. Lloyd at the Lawrence Livermore National Laboratory, Livermore, California applied for Patent US4251040 for large-scale wind power production by means of aerodynamically efficient kites.

Based on aircraft construction, these kites would fly transverse to the wind at high speed. The lift produced at this speed is sufficient to both support the kite and generate power. This would come to be known as crosswind kite power.

28 years later, Australian inventor Saul Griffith and kite designer Don Montague teamed  up to build a similar type of generator, calling their company ‘Makani’ after the Hawaiian word for wind.

Funded by DARPA, they built a 20 kW turbine-carrying glider and flew it in 2009; the higher the altitudes where the winds are stronger and more reliable, the more electrical energy is harvested. By 2011 Makani were testing developed models from the tarmac of the former Alameda Naval Air Station.

In 2013 they were bought up by Google. Although facing significant regulatory obstacles including wildlife preservation issues as well as the technological challenges, they were eventually able to produce their eighth generation prototype designed by Damon Vander Lind, a 600-kW carbon-fiber energy kite with eight rotors rotors each of 7.5 ft (2m³0) in diameter and with the 85 ft (26 m) wingspan of a small jet airliner.

The turbine driven generators would also function as motor-driven propellers in a powered flight mode, which could be used for vertical take-off and landing. A perch adapted to facilitate the take-off and landing would pivot such that the pivot is oriented towards the tension direction of the tether.

On May 18, 2017 the Makani 600-kW kite produced power for the first time. The rotation of the 85 ft. wide kite’s rotors drives magnet motors/generators on board, producing electricity that transfers down the tether where it can be connected to an energy grid.

The electricity comes down in DC (direct current), but is converted to AC (alternating current) at its base station. In February 2019, Royal Dutch Shell invested in the firm, but unfortunately during the COVID epidemic, Makani had to file for bankruptcy.

Similar projects are taking place in the Netherlands with the Ampyx tethered glider and in Norway with Kitemill and their Spark airplane. And Swiss startup Skypull has developed an autonomous drone that can fly to almost 2000 ft (600m) – about three times the height of a traditional wind turbine.

The Skypull current prototype is a rigid wing, multi-copter “box-wing” drone that can take off and land by itself, with no need for a launcher or ground wind. The take-off is battery-powered, but once in the air the battery is recharged every time the kite loops back down towards the ground.

Discover solution 9: electric airplanes

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Categories
Energy

4: Air conditioners that operate with water

Problem:

Leaking CFC and HCFC-based air conditioners contribute to GHG and ozone depletion.

Solution:

In 2018 a team of scientists at the National University of Singapore announced the development of a prototype of a sustainable air conditioning unit which uses water instead of refrigerants, and consumes 40 % less electricity to operate, and can cool a space to as low as 18° Celsius.

After four years of government-funded research on Project Drawdown, Dr. M. Kum Ja, Dr. Bui Duc Thuan, Associate Professor Ernest Chua, and Dr. Md Raisul Islam have produced two new technologies.

The first is a membrane dehumidifier which uses special water-absorbing materials and a difference in air pressure to extract water from ambient air as it is passed through the membrane.

The water removed is potable and almost as pure as bottled drinking water.

The drier air is then passed through what is called the counter-flow dew-point evaporative cooler, the team’s second invention.

This device removes heat through evaporative cooling, the same process that reduces body temperature through perspiration. Instead of relying on HCFCs, the drawdown air conditioner can cool a room using rain water.

It requires 2 pints (one liter) of water to cool a master bedroom unit for 15 to 20 hours. While regular air conditioners expel hot air as a by-product, the prototype releases humid air that is still likely to be cooler than ambient temperatures.

This helps to avoid disrupting the urban microclimate outside.

If a city replaces all its compressor-based coolers with this innovative air-conditioner, then it reduces its electrical demand enormously. Cities may slash their need for new power plants in developing countries, with a resource found wherever humans thrive.

In October 2018, team member Ernest Chua was conferred the Best Paper Award at the IEEE-organised “International Conference on Green Energy for Sustainable Development held in Phuket, Thailand. He also presented a paper in January 2019 at the World Economic Forum Annual Meeting at Davos.

He has emphasised that the 5 ft. (1.6 m) tall prototype was not the finished version, and his team is now looking to create a more compact and commercially viable product for the market in three to five years’ time. (nus.edu.sg)

Ernest Chua,“A hybrid air conditioning system employing membrane dehumidification and dew-point cooling” International Conference on Green Energy for Sustainable Development, October 2018

Discover solution 5: a bus that takes particles OUT of the air as it travels.

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Categories
Energy

3: Air breathing battery that exhales oxygen

Problem:

Li-ion cobalt batteries are difficult to produce and to recycle, hence expensive.

Solution:

A research team including Yet-Ming Chiang, the Kyocera Professor at the Massachusetts Institute of Technology has developed a type of battery which uses cheaper, abundant materials, and could be used for both short and long-term energy storage.

The researchers estimate that the total chemical cost of the battery could be as little as 1/30 the cost of current storage technologies, including li-ion.

The battery utilizes a sulfur anode (a by-product of fossil fuel production) dissolved in water of which there is an abundant supply, and an aerated liquid sodium salt solution in the cathode. Oxygen flowing in and out of the cathode causes the battery to discharge and charge.

This battery literally inhales and exhales air, but it does not exhale carbon dioxide, it exhales oxygen.

Although the initial prototype of the air-breathing sulfur flow battery was about the size of a coffee cup, flow batteries are known to be easily scalable and thanks to its low materials cost, the battery could be the first technology to compete in cost and energy density with pumped hydroelectric storage.

The battery has a slow self discharge rate, and could therefore be used in seasonal storage – an increasingly important concept as solar moves into regions further from the equator, where sunlight levels vary more greatly between seasons.

Soon after Yet-Ming Chiang and Mateo Jaramillo had founded Form Energy in Somerville, MA to market the battery, they were able to raise US$11 million, including US$9 million from Breakthrough Energy Ventures (BEV), launched by a group of billionaires including Bill Gates, Jeff Bezos, Jack Ma, Richard Branson, George Soros, Mark Zuckerberg, Masayoshi Son, and Michael Bloomberg.

In August 2019, Italian oil and gas major Eni signed on as lead investor, joined by Capricorn Investment Group and most of the existing investors from the original US$9 million, pushing it to US$40 million. (engine.xyz)

Yet-Ming Chiang et al., “Air-Breathing Aqueous Sulfur Flow Battery for Ultralow-Cost Long-Duration Electrical Storage” Joule. October 12, 2017.

Discover  solution 4: an air conditioner that uses water instead of
hydrofluorocarbons AND uses 40% less electricity

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